Thermal barrier coatings for substrates comprising titanium. The thermal barrier coating may include a bond layer, an insulating layer, and a sealant layer. The bond layer may include titanium, a titanium alloy, an intermetallic compound of titanium, and/or a titanium metal matrix composite.
The bond layer may have a superlattice structure having a periodically repeating group of layers. Methods for producing the thermal barrier coatings and articles of manufacture employing the thermal barrier coatings.

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